Cover Feature: Visible Light‐Induced Unactivated δ‐C(sp 3 )−H Amination of Alcohols Catalyzed by Iron (ChemSusChem 20/2022)
2022; Wiley; Volume: 15; Issue: 20 Linguagem: Inglês
10.1002/cssc.202201785
ISSN1864-564X
AutoresZhaofan Jue, Yahao Huang, Jiahui Qian, Peng Hu,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoThe Cover Feature shows a warrior directing a horse, originally from an alto-relievo of the Tang Dynasty in China. The picture is a metaphor of a visible-light-induced δ C(sp3)−H amination of aliphatic alcohols catalyzed with iron. The hydroxy substitute acts as the directing group to realize the selectivity of the reaction through an alkoxyl radical-involved 1,5-hydrogen atom transfer. More information can be found in the Research Article by Z. Jue et al.
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