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Carbon Monoxide as a Promoter for its own Oxidation on a Gold Electrode

2010; Wiley; Volume: 122; Issue: 7 Linguagem: Inglês

10.1002/ange.200905387

1521-3757

Paramaconi Rodríguez, Andrey A. Koverga, Marc T. M. Koper,

Electronic and Structural Properties of Oxides

Angewandte ChemieVolume 122, Issue 7 p. 1263-1265 Zuschrift Carbon Monoxide as a Promoter for its own Oxidation on a Gold Electrode† Paramaconi Rodríguez Dr., Paramaconi Rodríguez Dr. Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this authorAndrey A. Koverga, Andrey A. Koverga Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this authorMarc T. M. Koper Prof. Dr., Marc T. M. Koper Prof. Dr. m.koper@chem.leidenuniv.nl Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this author Paramaconi Rodríguez Dr., Paramaconi Rodríguez Dr. Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this authorAndrey A. Koverga, Andrey A. Koverga Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this authorMarc T. M. Koper Prof. Dr., Marc T. M. Koper Prof. Dr. m.koper@chem.leidenuniv.nl Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31) 71-527-4451 http://casc.lic.leidenuniv.nl/Search for more papers by this author First published: 01 February 2010 https://doi.org/10.1002/ange.200905387Citations: 9 † We acknowledge financial support from the Netherlands Organization for Scientific Research (NWO), the National Computer Facilities (NCF) for computing resources, and the European Commission (FP7 Initial Training Network "ELCAT", Grant Agreement No. 214936-2). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Treffpunkt Gold: Das vorgestellte Modell für die CO-Oxidation an Goldelektroden in alkalischem Medium geht davon aus, dass das CO die Adsorption des Oxidationsmittels verstärkt. Dies erklärt die Reaktionsordnung von größer 1 und die Beobachtung, dass gelöstes CO leichter oxidiert wird als adsorbiertes CO. DFT-Rechnungen bestätigen, dass CO und OH jeweils die Bindung des anderen Adsorbats auf Au(111) verstärken. C schwarz, O rot, H grau. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200905387_sm_miscellaneous_information.pdf73.3 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume122, Issue7February 8, 2010Pages 1263-1265 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation