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Triplet-DNP in magnetically oriented microcrystal arrays

2023; Elsevier BV; Volume: 351; Linguagem: Inglês

10.1016/j.jmr.2023.107439

1096-0856

Akinori Kagawa, Ryosuke Kusumi, Rintarou Nagase, Yuki Morishita, Koichiro Miyanishi, Kazuyuki Takeda, Masahiro Kitagawa, Makoto Negoro,

Synthesis and Properties of Aromatic Compounds

We explore dynamic nuclear polarization using electron spins in the photo-excited triplet state (Triplet-DNP) in magnetically oriented microcrystal arrays (MOMAs) of pentacene-doped p-terphenyl, in which the individual crystallites are magnetically aligned and UV-cured. In contrast to the conventional approach to Triplet-DNP in powder, which suffers from reduced nuclear polarization due to the averaged electron polarization and the broadening of electron-spin resonance, Triplet-DNP of the MOMAs offers as high dynamic polarization as that attainable in single-crystals. In the case of pentacene-doped p-terphenyl, the enhanced 1H polarization in the one-dimensional MOMA, prepared simply by leaving the suspension in a stationary magnetic field before UV curation, can be higher than that attainable in the powder sample by an order of magnitude and comparable to that in single crystals and in the three-dimensional MOMA made using a modulational rotating field. Triplet-DNP of the MOMAs may find potential applications, such as the polarization of the co-doped target molecules and dissolution experiments.