Organocatalytic photoinduced carboamination of dienes
2023; Royal Society of Chemistry; Volume: 59; Issue: 37 Linguagem: Inglês
10.1039/d3cc01121f
ISSN1364-548X
AutoresArun Kumar Yadav, Sabhya Sandha, Chandra Bhushan Tripathi,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoAn organocatalytic photoinduced 1,2-carbofunctionalization strategy for conjugated dienes has been developed. No exogenous photocatalyst or additives are required in this mild protocol and it allows for highly regioselective and efficient 1,2-carboisothiocyanation through the coupling of a diene, an alkyl radical and TMSNCS. The reaction is proposed to proceed through EDA complexation between the diene and TMSNCS.
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