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Exploration of the rare-earth cobalt nickel-based magnetocaloric materials for hydrogen liquefaction

2023; Elsevier BV; Volume: 159; Linguagem: Inglês

10.1016/j.jmst.2023.04.001

1941-1162

Yikun Zhang, Jiayu Ying, Xinqiang Gao, Zhaojun Mo, Jun Shen, Lingwei Li,

Shape Memory Alloy Transformations

Magnetic refrigeration based on the magnetocaloric effect (MCE) of magnetic solids has been considered as an emerging technology for hydrogen liquefaction. However, the lack of high-performance materials has slowed the development of any practical applications. Here, we present a family of rare-earth cobalt nickel-based magnetocaloric materials, namely Dy1-xHoxCoNi and Ho1-xErxCoNi compounds, and systematically investigated their structural and magnetic properties as well as the MCE and magnetocaloric performance. All of these compounds crystallize in the C15-type Laves-phase structure and undergo typical second-order magnetic phase transition (MPT). The change in magnetism and the MPT temperature for the Dy1-xHoxCoNi and Ho1-xErxCoNi compounds originate from the exchange interactions between nearest-neighbor RE3+ ion pairs. No hysteresis magnetocaloric effect was achieved, and the MPT temperature of these compounds could be tuned from the liquefaction temperature of nitrogen (∼77 K) to hydrogen (∼20 K) by adjusting the ratio of rare-earth elements. This study's findings indicate that the Dy1-xHoxCoNi and Ho1-xErxCoNi compounds are of potential for practical magnetic refrigeration applications in the field of hydrogen liquefaction.