Portal de Periódicos da CAPES

NiCo‐glycolate‐derived porous spherical NiCo 2 S 4 for high‐performance asymmetric supercapacitors

2023; Wiley; Volume: 37; Issue: 12 Linguagem: Inglês

10.1002/aoc.7301

1099-0739

Maiyong Zhu, Congcong Lu, Yunping Ma, Yu Yang,

Electrocatalysts for Energy Conversion

The construction of electrode materials with high rate and excellent cycling stability is the key to supercapacitors. Due to their remarkable high conductivity and great electrochemical activity, transition bimetallic sulfides are extremely appealing electrode materials for supercapacitors, but their synthesis is still challenging. In this study, a NiCo bimetallic sulfide (NiCo 2 S 4 ) microspheres with porous structure were prepared via direct vulcanization of NiCo‐EG complexes followed by a thermal treatment, which were pre‐synthesized via coordination of ethylene glycol (EG) with transition metal ions (Ni 2+ , Co 2+ ) under hydrothermal condition. Some experimental parameters were investigated, including the control of NiCo 2 S 4 microspheres produced by the ratio of precursor NiCo‐EG to different masses of sulfur sources, which in turn affects the electrochemical properties. When applied as electrode for supercapacitor, the NiCo 2 S 4 microspheres obtained under optimal condition delivered a high capacitance (1386 F g −1 at 1 A g −1 ), excellent rate capability (845 F g −1 at 10 A g −1 ) and stable cycling performance (80.05% after 5000 cycles at 10 A/g). Furthermore, for checking the practicality of the produced NiCo 2 S 4 microspheres, an asymmetric supercapacitor device was built using activated carbon (AC) as the negative electrode and NiCo 2 S 4 microspheres as the positive electrode. The assembled NiCo 2 S 4 //AC cell had a power density of 799.9 W kg −1 and an energy density of 30.5 Wh kg −1 , confirming that the structurally optimized NiCo 2 S 4 porous nanomicrospheres have excellent electrochemical properties and have a wide range of application prospects.