Radical Cation Salts of Hetera‐Buckybowls: Polar Crystals, Negative Thermal Expansion and Phase Transition
2024; Wiley; Volume: 63; Issue: 12 Linguagem: Inglês
10.1002/anie.202319587
ISSN1521-3773
AutoresLingxi Wu, Yecheng Li, Xinqiang Hua, Lei Ye, Chengshan Yuan, Zitong Liu, Hao‐Li Zhang, Xiangfeng Shao,
Tópico(s)Advanced Battery Materials and Technologies
ResumoRadical cation salts of π-conjugated polycycles are rich in physical properties. Herein, two kinds of hetera-buckybowls, ethoxy-substituted trithiasumanene (3SEt) and triselenasumanene (3SeEt), are synthesized as electron donors. Galvanostatic oxidation of them affords radical cation salts (3SEt)
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