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Revealing the Potential and Challenges of High‐Entropy Layered Cathodes for Sodium‐Based Energy Storage

2024; Wiley; Volume: 14; Issue: 20 Linguagem: Inglês

10.1002/aenm.202304529

1614-6840

Hong Gao, Jiayi Li, Fan Zhang, Congcong Li, Jun Xiao, Xinming Nie, Gui-Lai Zhang, Yang Xiao, Dingyi Zhang, Xin Guo, Yong Wang, Yong‐Mook Kang, Guoxiu Wang, Hao Liu,

Advanced Battery Materials and Technologies

Abstract Sodium‐ion batteries (SIBs) reflect a strategic move for scalable and sustainable energy storage. The focus on high‐entropy (HE) cathode materials, particularly layered oxides, has ignited scientific interest due to the unique characteristics and effects to tackle their shortcomings, such as inferior structural stability, sluggish reaction kinetics, severe Jahn‐Teller effects induced lattice distortion, and poor oxygen reversibility at high voltage. This review focuses on high‐entropy oxide materials, highlighting their fundamentals, design principles, and application in layered oxide cathodes for SIBs. It delves into the growth mechanism, composition‐properties correlations, and the functional roles of high‐entropy design in enhancing the performance of layered oxide cathodes. Furthermore, it furnishes a comprehensive survey of recent advancements and persisting challenges within the domain of layered high‐entropy cathode materials, as well as offers insights into potential future research directions in line with the current state of knowledge.