CHARACTERIZATION OF NEW MIXED AND HYBRID INORGANIC-ORGANIC MATERIALS BASED ON PHOSPHATES BY INFRARED SPECTROSCOPY
2024; Volume: 12; Issue: 11 Linguagem: Inglês
10.21474/ijar01/19886
ISSN2320-5407
AutoresDame Seye, Lamine Yaffa, Momath Lo, Assane Touré, Diadioly Gassama, Cheikh Diop,
Tópico(s)Inorganic and Organometallic Chemistry
ResumoIn this work we synthesized three inorganic-organic hybrid organic phosphate compounds of current interest due to their fascinating architectures and potential applications in supramolecular chemistry engineeringThese compounds were characterized mainly by elementary analysis and IR spectroscopies. they were synthesized from a reaction carried out in a common organic solvent between the monocyclohexylamine phosphate and〖SnBu〗_2 〖Cl〗_2 〖Y(CH〗_3 〖CO〗_2 )_(3.) or D_y 〖Cl〗_3.. Structures involving complex anions have been proposed. Structures involving complex anions have been proposed. In phosphate compounds, the anion is present in the form of〖HPO〗_4^(2-)and 〖HPO〗_4^(2-)The structures obtained are of the infinite type, monomer or with double metallic components. Phosphato compounds with rare earths gave new monomeric or double metallic component structures. The nine coordination (9) found in one of the metallic components is a coordination that we find with rare earths. The structural study of its complexes has shown that these cordination complexes can present promising catalytic activity for the oxidation and degradation of compounds such as methylene blue.
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